キセノン

導入

原子番号: 54
グループ: 18 or VIII A
原子量: 131.293
期間: 5
CAS番号: 7440-63-3

分類

カルコゲン
ハロゲン
希ガス
ランタノイド元素
アクチノイド元素
希土類元素
プラチナグループメタル
超ウラン
いいえ安定同位体ません
固体
液体
ガス
固体 (予測)

説明 • 用途/機能

Discovered by Ramsay and Travers in 1898 in the residue left after evaporating liquid air components. Xenon isa member of the so-called noble or “inert” gases. It is present in the atmosphere to the extent of about one part in twenty million. Xenon is present inthe Martian atmosphere to the extent of 0.08 ppm. The element is found in the gases evolved from certain mineral springs, and is commercially obtainedby extraction from liquid air. Natural xenon is composed of nine stable isotopes. In addition to these, thirty five unstable isotopes and isomers havebeen characterized. Before 1962, it had generally been assumed that xenon and other noble gases were unable to form compounds. Evidence has beenmounting in the past few years that xenon, as well as other members of the zero valence elements, do form compounds. Among the “compounds” ofxenon now reported are xenon hydrate, sodium perxenate, xenon deuterate, difluoride, tetrafluoride, hexafluoride, and XePtf6 and XeRhf6. Xenontrioxide, which is highly explosive, has been prepared. More than 80 xenon compounds have been made with xenon chemically bonded to fluorineand oxygen. Some xenon compounds are colored. Metallic xenon has been produced, using several hundred kilobars of pressure. Xenon in a vacuumtube produces a beautiful blue glow when excited by an electrical discharge. The gas is used in making electron tubes, stroboscopic lamps, bactericidallamps, and lamps used to excite ruby lasers for generating coherent light. Xenon is used in the atomic energy field in bubble chambers, probes, andother applications where its high molecular weight is of value. The perxenates are used in analytical chemistry as oxidizing agents. 133Xe and 135Xeare produced by neutron irradiation in air cooled nuclear reactors. 133Xe has useful applications as a radioisotope. The element is available in sealedglass containers for about $20/L of gas at standard pressure. Xenon is not toxic, but its compounds are highly toxic because of their strong oxidizingcharacteristics. 1

• "Krypton and xenon are likewise used, but to a much smaller extent, in the filling of fluorescent lamps and other special lamps." 2
• "Xe and Kr mixture in high-intensity, short-exposure photographic flash tubes" 3

物理的特性

融点:4
沸点:4* -108.12 °C = 165.03 K = -162.616 °F
昇華点:4 
三重点:4 -111.79 °C = 161.36 K = -169.222 °F at 81.6 kPa
臨界点:4 16.62 °C = 289.77 K = 61.916 °F 4
密度:5  5.366 g/L

* - at 1 atm

電子構成

電子構成: [Kr] 5s2 4d10 5p6
ブロック: p
最高占有エネルギーレベル: 5
ヴァランス電子: 8

量子数:

n = 5
ℓ = 1
m = 1
ms = -½

ボンディング

電気陰性度 (ポーリングスケール):6 2.60
Electropositivity (ポーリングスケール): 1.4
電子親和力:7 not stable eV
酸化状態: 0

イオン化ポテンシャル   eV 8  kJ/mol  
1 12.1298    1170.3
イオン化ポテンシャル   eV 8  kJ/mol  
2 21.20979    2046.4
イオン化ポテンシャル   eV 8  kJ/mol  
3 32.123    3099.4

熱化学

比熱: 0.158 J/g°C 9 = 20.744 J/mol°C = 0.038 cal/g°C = 4.958 cal/mol°C
熱伝導率: 0.00569 (W/m)/K, 27°C 10
融解熱: 2.297 kJ/mol 11 = 17.5 J/g
気化熱: 12.636 kJ/mol 12 = 96.2 J/g
物質の状態 生成エンタルピー (ΔHf°)13 エントロピ (S°)13 ギブズ自由エネルギー (ΔGf°)13
(kcal/mol) (kJ/mol) (cal/K) (J/K) (kcal/mol) (kJ/mol)
(g) 0 0 40.529 169.573336 0 0

同位体

核種 質量 14 人生の半分 14 核スピン 14 結合エネルギー
110Xe 109.94428(14) 310(190) ms [105(+35-25) ms] 0+ 901.49 MeV
111Xe 110.94160(33)# 740(200) ms 5/2+# 909.56 MeV
112Xe 111.93562(11) 2.7(8) s 0+ 926.94 MeV
113Xe 112.93334(9) 2.74(8) s (5/2+)# 935.02 MeV
114Xe 113.927980(12) 10.0(4) s 0+ 952.40 MeV
115Xe 114.926294(13) 18(4) s (5/2+) 960.47 MeV
116Xe 115.921581(14) 59(2) s 0+ 968.54 MeV
117Xe 116.920359(11) 61(2) s 5/2(+) 976.62 MeV
118Xe 117.916179(11) 3.8(9) min 0+ 994.00 MeV
119Xe 118.915411(11) 5.8(3) min 5/2(+) 1,002.07 MeV
120Xe 119.911784(13) 40(1) min 0+ 1,010.14 MeV
121Xe 120.911462(12) 40.1(20) min (5/2+) 1,018.22 MeV
122Xe 121.908368(12) 20.1(1) h 0+ 1,035.60 MeV
123Xe 122.908482(10) 2.08(2) h 1/2+ 1,043.67 MeV
124Xe 123.905893(2) STABLE 0+ 1,051.74 MeV
125Xe 124.9063955(20) 16.9(2) h 1/2(+) 1,059.82 MeV
126Xe 125.904274(7) STABLE 0+ 1,067.89 MeV
127Xe 126.905184(4) 36.345(3) d 1/2+ 1,075.96 MeV
128Xe 127.9035313(15) STABLE 0+ 1,084.03 MeV
129Xe 128.9047794(8) STABLE 1/2+ 1,092.10 MeV
130Xe 129.9035080(8) STABLE 0+ 1,100.17 MeV
131Xe 130.9050824(10) STABLE 3/2+ 1,108.24 MeV
132Xe 131.9041535(10) STABLE 0+ 1,116.32 MeV
133Xe 132.9059107(26) 5.2475(5) d 3/2+ 1,124.39 MeV
134Xe 133.9053945(9) STABLE 0+ 1,132.46 MeV
135Xe 134.907227(5) 9.14(2) h 3/2+ 1,140.53 MeV
136Xe 135.907219(8) STABLE 0+ 1,148.60 MeV
137Xe 136.911562(8) 3.818(13) min 7/2- 1,147.36 MeV
138Xe 137.91395(5) 14.08(8) min 0+ 1,155.43 MeV
139Xe 138.918793(22) 39.68(14) s 3/2- 1,163.50 MeV
140Xe 139.92164(7) 13.60(10) s 0+ 1,162.26 MeV
141Xe 140.92665(10) 1.73(1) s 5/2(-#) 1,170.33 MeV
142Xe 141.92971(11) 1.22(2) s 0+ 1,178.40 MeV
143Xe 142.93511(21)# 0.511(6) s 5/2- 1,177.15 MeV
144Xe 143.93851(32)# 0.388(7) s 0+ 1,185.23 MeV
145Xe 144.94407(32)# 188(4) ms (3/2-)# 1,183.98 MeV
146Xe 145.94775(43)# 146(6) ms 0+ 1,192.05 MeV
147Xe 146.95356(43)# 130(80) ms [0.10(+10-5) s] 3/2-# 1,190.81 MeV
値は、#は、純粋に実験データから派生しますが、少なくとも部分的に体系的な傾向からしていないとマーク。弱い代入引数は括弧で囲まれていてスピン。 14

豊富

地球 - ソース化合物: uncombined 15
地球 - 海水: 0.00005 mg/L 16
地球 -  地殻:  0.00003 mg/kg = 0.000000003% 16
地球 -  合計:  0.0168E-8 cm^3/g 17
マーキュリー(惑星) -  合計:  17
金星 -  合計:  1.61E-8 cm^3/g 17
コンドライト - 合計: 0.7×10-5 (relative to 106 atoms of Si) 18

化合物

安全情報


安全データシート - ACI Alloys, Inc.

詳細については

外部リンク:

ソース

(1) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:34-4:35.
(2) - Jolly, William L. The Chemistry of the Non-Metals; Prentice-Hall: Englewood Cliffs, New Jersey, 1966; p 23.
(3) - Whitten, Kenneth W., Davis, Raymond E., and Peck, M. Larry. General Chemistry 6th ed.; Saunders College Publishing: Orlando, FL, 2000; p 944.
(4) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:132.
(5) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 4:39-4:96.
(6) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 10:147-10:148.
(7) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 10:178 - 10:180.
(8) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:133.
(9) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:193, 12:219-220.
(10) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:123-6:137.
(11) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:107-6:122.
(12) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(13) - Atomic Mass Data Center. http://amdc.in2p3.fr/web/nubase_en.html (accessed July 14, 2009).
(14) - Silberberg, Martin S. Chemistry: The Molecular Nature of Matter and Change, 4th ed.; McGraw-Hill Higher Education: Boston, MA, 2006, p 965.
(15) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 14:17.
(16) - Morgan, John W. and Anders, Edward, Proc. Natl. Acad. Sci. USA 77, 6973-6977 (1980)
(17) - Brownlow, Arthur. Geochemistry; Prentice-Hall, Inc.: Englewood Cliffs, NJ, 1979, pp 15-16.