NOBELIUM

Introdução

Número atômico: 102
Grupo: Nenhum
Peso atômico: 259
Período: 7
Número CAS: 10028-14-5

Classificação

Calcogênio
halogênio
Gás nobre
Lantanóides
Actinóide
Terra-rara
Platinum Metal Group
Transuranium
Não Isótopos Estáveis
Sólido
Líquido
Gás
Sólido (previsto)

Descrição • Usos / Função

Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J. R. Walton, and G. T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95% curium-244 and 4.5% curium-246) with carbon-12 ions to produce Element 102-254 according to the curium-246 (carbon-12, 4 neutrons) reaction. Earlier in 1957 workers of the U.S., Britain, and Sweden announced the discovery of an isotope of Element 102 with a 10-min half-life at 8.5 MeV, as a result of bombarding curium-244 with carbon-13 nuclei. On the basis of this experiment the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry. The acceptance of the name was premature, for both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 ± 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support claim to discovery. Confirmatory experiments at Berkeley in 1966 have shown the existence of Element 102-254 with a 55-s half-life, Element 102-252 with a 2.3-s half-life, and Element 102-257 with a 25-s half-life. Twelve isotopes are now recognized, one of which — Element 102-255 has a half-life of 3.1 min. In view of the discover’s traditional right to name an element, the Berkeley group, in 1967, suggested that the hastily given name nobelium, along with the symbol No, be retained. 1

Propriedades físicas

Ponto de fusão:2*  827 °C = 1100.15 K = 1520.6 °F
Ponto de ebulição:2
Ponto de sublimação:2 
Ponto Triplo:2 
Ponto crítico:2 
Densidade:   g/cm3

* - at 1 atm

Configuração Electron

Configuração Electron:  *[Rn] 7s2 5f14
Quadra: f
Mais alto nível de energia Ocupado: 7
Elétrons de valência: 2

Números quânticos:

n = 5
ℓ = 3
m = 3
ms = -½

Colagem

potencial de ionização   eV 3  kJ/mol  
potencial de ionização   eV 3  kJ/mol  
potencial de ionização   eV 3  kJ/mol  
1 6.65    641.6

Termoquímica

Calor específico: 
Condutividade térmica: 10 (W/m)/K, 27°C 4
Calor de fusão: 
Calor da vaporização: 
Estado da matéria Entalpia de formação (ΔHf°)5 entropia (S°)5 Gibbs Energia Livre (ΔGf°)5
(kcal/mol) (kJ/mol) (cal/K) (J/K) (kcal/mol) (kJ/mol)
(g) 21.57 90.24888 50.347 210.651848 20.69 86.56696

isótopos

nuclide Massa 6 Meia vida 6 spin nuclear 6 Energia de ligação
248No 248.08660(32)# <2 μs 0+ 1,847.36 MeV
249No 249.08783(37)# 57(12) μs [54(+15-10) μs] 5/2+# 1,855.44 MeV
250No 250.08751(22)# 5.7(8) μs 0+ 1,863.51 MeV
251No 251.08901(19)# 0.78(2) s 7/2+# 1,871.58 MeV
252No 252.088977(14) 2.27(14) s 0+ 1,879.65 MeV
253No 253.09068(11)# 1.62(15) min (9/2-)# 1,878.41 MeV
254No 254.090955(19) 51(10) s 0+ 1,886.48 MeV
255No 255.093241(11) 3.1(2) min (1/2+) 1,894.55 MeV
256No 256.094283(8) 2.91(5) s 0+ 1,902.62 MeV
257No 257.096877(23) 25(2) s (7/2+) 1,910.69 MeV
258No 258.09821(22)# 1.2(2) ms 0+ 1,918.76 MeV
259No 259.10103(11)# 58(5) min (9/2+)# 1,917.52 MeV
260No 260.10264(22)# 106(8) ms 0+ 1,925.59 MeV
261No 261.10575(32)# 3# h 3/2+# 1,933.66 MeV
262No 262.10730(48)# ~5 ms 0+ 1,941.73 MeV
263No 263.11055(53)# 20# min 1,940.49 MeV
264No 264.11235(69)# 1# min 0+ 1,948.56 MeV
Os valores marcados # não são puramente derivado a partir de dados experimentais, mas, pelo menos, parcialmente a partir de tendências sistemáticas. Gira com argumentos de atribuição fracos estão entre parênteses. 6

reações

Abundância

Informação de Segurança


Material Safety Data Sheet - ACI Alloys, Inc.

Para maiores informações

Links externos:

Fontes

(1) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:21.
(2) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:132.
(3) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 10:178 - 10:180.
(4) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:193, 12:219-220.
(5) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:123-6:137.
(6) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:107-6:122.
(7) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(8) - Atomic Mass Data Center. http://amdc.in2p3.fr/web/nubase_en.html (accessed July 14, 2009).
(9) - Zumdahl, Steven and Zumdahl, Susan A. Chemistry 9th ed.; Brooks/Cole: Belmont, CA, 2014; p 132.
(10) - Halka, Monica and Nordstrom, Brian. Metals & Metalloids; Infobase Publishing: New York, NY, 2011; pg. 96.
(11) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; p 135.
(12) - Swaddle, T.W. Inorganic Chemistry; Academic Press: San Diego, 1997; p 360.
(13) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; pp 223-4, 302.
(14) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; pp 135, 138, 194, 210, 219, 222, 224, 227.
(15) - Kotz, John C., Treichel, Paul, and Weaver, Gabriela. Chemistry & Chemical Reactivity 6th ed.; Thomson Brooks/Cole: Belmont, CA, 2006; p 166.
(16) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; pp 219, 302.
(17) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; p 138.
(18) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; pp 211, 219.
(19) - Halka, Monica and Nordstrom, Brian. Metals & Metalloids; Infobase Publishing: New York, NY, 2011; pg. 49.