Giới thiệu
Nhóm: 5 or V B
trọng lượng nguyên tử: 50.9415
Giai đoạn: 4
Số CAS: 7440-62-2
phân loại
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Chất rắn
Chất lỏng
Khí
Chất rắn (Dự đoán)
Sự miêu tả • Sử dụng / Chức năng
Vanadium was first discovered by del Rio in 1801. Unfortunately, a French chemist incorrectly declared del Rio’s new element was onlyimpure chromium; del Rio thought himself to be mistaken and accepted the French chemist’s statement. The element was rediscovered in 1830 bySefstrom, who named the element in honor of the Scandinavian goddess Vanadis because of its beautiful multicolored compounds. It was isolated innearly pure form by Roscoe, in 1867, who reduced the chloride with hydrogen. Vanadium of 99.3 to 99.8% purity was not produced until 1927.Vanadium is found in about 65 different minerals among which are carnotite, roscoelite, vanadinite, and patronite important sources of the metal.Vanadium is also found in phosphate rock and certain iron ores, and is present in some crude oils in the form of organic complexes. It is also foundin small percentages in meteorites. Commercial production from petroleum ash holds promise as an important source of the element. High-purityductile vanadium can be obtained by reduction of vanadium trichloride with magnesium or with magnesium-sodium mixtures. Much of the vanadiummetal being produced is now made by calcium reduction of V2O5 in a pressure vessel, an adaption of a process developed by McKechnie and Seybolt.Natural vanadium is a mixture of two isotopes, 50V (0.25%) and 51V (99.75%). 50V is slightly radioactive, having a long half-life. Seventeen otherunstable isotopes are recognized. Pure vanadium is a bright white metal, and is soft and ductile. It has good corrosion resistance to alkalis, sulfuricand hydrochloric acid, and salt water, but the metal oxidizes readily above 660°C. The metal has good structural strength and a low fission neutroncross section, making it useful in nuclear applications. Vanadium is used in producing rust resistant, spring, and highspeed tool steels. It is an importantcarbide stabilizer in making steels. About 80% of the vanadium now produced is used as ferrovanadium or as a steel additive. Vanadium foil is usedas a bonding agent in cladding titanium to steel. Vanadium pentoxide is used in ceramics and as a catalyst. It is also used in producing a superconductivemagnet with a field of 175,000 gauss. Vanadium and its compounds are toxic and should be handled with care. Ductile vanadium is commerciallyavailable. Commercial vanadium metal, of about 95% purity, costs about $50kg. Vanadium metal (99.7%) costs about $1.50/g or $700/kg. 1
• "Vanadium gives steel the ability to resist breakage under heavy shocks, and permits steel springs to be bent countless times without losing their elasticity." 2
• "A number of transition metals (Ti, Zr, Hf, V, Nb, Ta, Mo, W) form interstitial carbides of composition MC and, in some cases, M2C. These carbides have extremely high melting points; they are very hard, and they are good electrical conductors." 3
Tính chất vật lý
Độ nóng chảy:4* 1910 °C = 2183.15 K = 3470 °F
electron Cấu hình: [Ar] 4s2 3d3
n = 3
Độ âm điện (thang Pauling):6 1.63
Nhiệt dung riêng: 0.489 J/g°C 10 = 24.910 J/mol°C = 0.117 cal/g°C = 5.954 cal/mol°C
trái đất - nguồn hợp chất: oxides 16
Liện kết ngoại:
(1) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:34.
Điểm sôi:4* 3407 °C = 3680.15 K = 6164.6 °F
điểm thăng hoa:4
ba điểm:4
Điểm cốt lõi:4
Tỉ trọng:5 6.0 g/cm3
* - at 1 atm
electron Cấu hình
Khối: d
Cao nhất Chiếm Năng lượng Cấp: 4
Valence electron:
số lượng tử:
ℓ = 2
mℓ = 0
ms = +½
bonding
Electropositivity (thang Pauling): 2.37
electron Affinity:7 0.525 eV
Quá trình oxy hóa Hoa: +5,2,3,4
Chức năng làm việc:8 4.44 eV = 7.11288E-19 J
ion hóa tiềm năng
eV 9
kJ/mol
1
6.7462
650.9
2
14.66
1414.5
3
29.311
2828.1
4
46.709
4506.7
5
65.2817
6298.7
6
128.13
12362.7
7
150.6
14530.7
ion hóa tiềm năng
eV 9
kJ/mol
8
173.4
16730.6
9
205.8
19856.7
10
230.5
22239.9
11
255.7
24671.3
12
308.1
29727.1
13
336.277
32445.8
14
896
86450.8
15
976
94169.7
ion hóa tiềm năng
eV 9
kJ/mol
16
1060
102274.4
17
1168
112694.8
18
1260
121571.5
19
1355
130737.6
20
1486
143377.2
21
1569.6
151443.3
22
6851.3
661049.8
23
7246.12
699144.1
nhiệt hóa học
Dẫn nhiệt: 30.7 (W/m)/K, 27°C 11
Nhiệt Fusion: 20.9 kJ/mol 12 = 410.3 J/g
Nhiệt bay hơi: 0.452 kJ/mol 13 = 8.9 J/g
Nhà nước Matter
Entanpi của Formation (ΔHf°)14
entropy (S°)14
Gibbs miễn phí năng lượng (ΔGf°)14
(kcal/mol)
(kJ/mol)
(cal/K)
(J/K)
(kcal/mol)
(kJ/mol)
(s)
0
0
6.91
28.91144
0
0
(g)
122.90
514.2136
43.544
182.188096
108.32
453.21088
Đồng vị
Nuclide
Khối lượng 15
Half-Life 15
spin hạt nhân 15
Ràng buộc năng lượng
40V
40.01109(54)#
2-#
294.61 MeV
41V
40.99978(22)#
7/2-#
313.86 MeV
42V
41.99123(21)#
<55 ns
2-#
329.38 MeV
43V
42.98065(25)#
80# ms
7/2-#
347.70 MeV
44V
43.97411(13)
111(7) ms
(2+)
361.36 MeV
45V
44.965776(18)
547(6) ms
7/2-
377.82 MeV
46V
45.9602005(11)
422.50(11) ms
0+
390.55 MeV
47V
46.9549089(9)
32.6(3) min
3/2-
404.21 MeV
48V
47.9522537(27)
15.9735(25) d
4+
414.14 MeV
49V
48.9485161(12)
329(3) d
7/2-
425.94 MeV
50V
49.9471585(11)
1.4(4)E17 a
6+
434.94 MeV
51V
50.9439595(11)
ỔN ĐỊNH
7/2-
446.74 MeV
52V
51.9447755(11)
3.743(5) min
3+
453.88 MeV
53V
52.944338(3)
1.60(4) min
7/2-
461.95 MeV
54V
53.946440(16)
49.8(5) s
3+
468.16 MeV
55V
54.94723(11)
6.54(15) s
(7/2-)#
475.30 MeV
56V
55.95053(22)
216(4) ms
(1+)
480.57 MeV
57V
56.95256(25)
0.35(1) s
(3/2-)
486.78 MeV
58V
57.95683(27)
191(8) ms
3+#
491.13 MeV
59V
58.96021(33)
75(7) ms
7/2-#
495.47 MeV
60V
59.96503(51)
122(18) ms
3+#
498.89 MeV
61V
60.96848(43)#
47.0(12) ms
7/2-#
504.16 MeV
62V
61.97378(54)#
33.5(20) ms
3+#
507.58 MeV
63V
62.97755(64)#
17(3) ms
(7/2-)#
511.92 MeV
64V
63.98347(75)#
10# ms [>300 ns]
514.41 MeV
65V
64.98792(86)#
10# ms
5/2-#
518.75 MeV
Các giá trị được đánh dấu # được không hoàn toàn xuất phát từ số liệu thực nghiệm, nhưng ít nhất một phần từ các xu hướng có hệ thống. Quay với lập luận phân yếu được kèm theo trong ngoặc đơn. 15
phong phú
trái đất - Nước biển: 0.0025 mg/L 17
trái đất -
vỏ trái đất:
120 mg/kg = 0.012% 17
trái đất -
Thạch quyển:
0.014% 18
trái đất -
Tổng số:
82 ppm 19
Mercury (hành tinh) -
Tổng số:
63 ppm 19
sao Kim -
Tổng số:
86 ppm 19
chondrite - Tổng số: 200 (relative to 106 atoms of Si) 20
Các hợp chất
vanadium(II) bromide
vanadium(II) chloride
vanadium(II) fluoride
vanadium(II) iodide
vanadium(II) oxide
vanadium(II) silicide
vanadium(III) bromide
vanadium(III) chloride
vanadium(III) fluoride
Thông tin an toàn
Bảng dữ liệu an toàn vật liệu - ACI Alloys, Inc.
Để biết thêm thông tin
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nguồn
(2) - Brownlee, Raymond B., Fuller, Robert W., and Whitsit, Jesse E. Elements of Chemistry; Allyn and Bacon: Boston, Massachusetts, 1959; p 560.
(3) - Jolly, William L. The Chemistry of the Non-Metals; Prentice-Hall: Englewood Cliffs, New Jersey, 1966; p 119.
(4) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:132.
(5) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 4:39-4:96.
(6) - Dean, John A. Lange's Handbook of Chemistry, 11th ed.; McGraw-Hill Book Company: New York, NY, 1973; p 4:8-4:149.
(7) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 10:147-10:148.
(8) - Speight, James. Lange's Handbook of Chemistry, 16th ed.; McGraw-Hill Professional: Boston, MA, 2004; p 1:132.
(9) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 10:178 - 10:180.
(10) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:133.
(11) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:193, 12:219-220.
(12) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:123-6:137.
(13) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:107-6:122.
(14) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(15) - Atomic Mass Data Center. http://amdc.in2p3.fr/web/nubase_en.html (accessed July 14, 2009).
(16) - Silberberg, Martin S. Chemistry: The Molecular Nature of Matter and Change, 4th ed.; McGraw-Hill Higher Education: Boston, MA, 2006, p 965.
(17) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 14:17.
(18) - Silberberg, Martin S. Chemistry: The Molecular Nature of Matter and Change, 4th ed.; McGraw-Hill Higher Education: Boston, MA, 2006, p 964.
(19) - Morgan, John W. and Anders, Edward, Proc. Natl. Acad. Sci. USA 77, 6973-6977 (1980)
(20) - Brownlow, Arthur. Geochemistry; Prentice-Hall, Inc.: Englewood Cliffs, NJ, 1979, pp 15-16.