介绍

原子数: 89
组: 3 or III B
原子量: 227
期: 7
CAS号码: 7440-34-8

分类

金属
非金属
非金属
碱金属
碱土金属
过渡金属
硫族
卤素
惰性气体
镧系元素

稀土元素
铂族金属
超铀
没有稳定的同位素
固体
液体
加油站
固体 (预料到的)

描述 • 用途/功能

Discovered by Andre Debierne in 1899 and independently by F. Giesel in 1902. Occurs naturally in association with uranium minerals. Thirty two isotopes and isomers are now recognized. All are radioactive. Actinium-227, a decay product of uranium-235, is an alpha and beta emitter with a 21.77-year halflife. Its principal decay products are thorium-227 (18.72-day half-life), radium-223 (11.4-day half-life), and a number of short-lived products including radon, bismuth, polonium, and lead isotopes. In equilibrium with its decay products, it is a powerful source of alpha rays. Actinium metal has been prepared by the reduction of actinium fluoride with lithium vapor at about 1100 to 1300°C. The chemical behavior of actinium is similar to that of the rare earths, particularly lanthanum. Purified actinium comes into equilibrium with its decay products at the end of 185 days, and then decays according to its 21.77-year half-life. It is about 150 times as active as radium, making it of value in the production of neutrons. 1

物理性能

熔点:2*  1051 °C = 1324.15 K = 1923.8 °F
沸点:2* 3198 °C = 3471.15 K = 5788.4 °F
升华点:2 
三相点:2 
临界点:2 
密度:3  10 g/cm3

* - at 1 atm

电子组态

电子组态:  *[Rn] 7s2 5f1
块: d
最高占据能级: 7
价电子: 

量子数:

n = 5
ℓ = 3
m = -3
ms = +½

粘接

电负性 (鲍林规模):4 1.1
Electropositivity (鲍林规模): 2.9
电子亲:5 0.35 eV
氧化态: +3

电离能   eV 6  kJ/mol  
电离能   eV 6  kJ/mol  
1 5.17    498.8
电离能   eV 6  kJ/mol  
2 12.1    1167.5

热化学

比热: 0.120 J/g°C 7 = 27.240 J/mol°C = 0.029 cal/g°C = 6.511 cal/mol°C
导热系数: 12 (W/m)/K, 27°C 8
融合热: 
汽化热: 
物质状态 生成焓 (ΔHf°)9 熵 (S°)9 吉布斯自由能 (ΔGf°)9
(kcal/mol) (kJ/mol) (cal/K) (J/K) (kcal/mol) (kJ/mol)
(s) 0 0 15.00 62.76 0 0
(g) 94.0 393.296
(s) 0.0 0 56.5 236.396
(g) 406.0 1698.704 188.1 787.0104 366.0 1531.344

同位素

核素  10 半衰期 10 核自旋 10 结合能
206Ac 206.01450(8) 25(7) ms (3+) 1,583.74 MeV
207Ac 207.01195(6) 31(8) ms [27(+11-6) ms] 9/2-# 1,591.82 MeV
208Ac 208.01155(6) 97(16) ms [95(+24-16) ms] (3+) 1,599.89 MeV
209Ac 209.00949(5) 92(11) ms (9/2-) 1,617.27 MeV
210Ac 210.00944(6) 350(40) ms 7+# 1,625.35 MeV
211Ac 211.00773(8) 213(25) ms 9/2-# 1,633.42 MeV
212Ac 212.00781(7) 920(50) ms 6+# 1,641.49 MeV
213Ac 213.00661(6) 731(17) ms (9/2-)# 1,649.56 MeV
214Ac 214.006902(24) 8.2(2) s (5+)# 1,657.63 MeV
215Ac 215.006454(23) 0.17(1) s 9/2- 1,665.70 MeV
216Ac 216.008720(29) 0.440(16) ms (1-) 1,673.77 MeV
217Ac 217.009347(14) 69(4) ns 9/2- 1,681.84 MeV
218Ac 218.01164(5) 1.08(9) μs (1-)# 1,680.60 MeV
219Ac 219.01242(5) 11.8(15) μs 9/2- 1,688.67 MeV
220Ac 220.014763(16) 26.36(19) ms (3-) 1,696.74 MeV
221Ac 221.01559(5) 52(2) ms 9/2-# 1,704.81 MeV
222Ac 222.017844(6) 5.0(5) s 1- 1,712.89 MeV
223Ac 223.019137(8) 2.10(5) min (5/2-) 1,720.96 MeV
224Ac 224.021723(4) 2.78(17) h 0- 1,719.71 MeV
225Ac 225.023230(5) 10.0(1) d (3/2-) 1,727.79 MeV
226Ac 226.026098(4) 29.37(12) h (1)(-#) 1,735.86 MeV
227Ac 227.0277521(26) 21.772(3) a 3/2- 1,743.93 MeV
228Ac 228.0310211(27) 6.15(2) h 3+ 1,742.68 MeV
229Ac 229.03302(4) 62.7(5) min (3/2+) 1,750.76 MeV
230Ac 230.03629(32) 122(3) s (1+) 1,758.83 MeV
231Ac 231.03856(11) 7.5(1) min (1/2+) 1,766.90 MeV
232Ac 232.04203(11) 119(5) s (1+) 1,765.65 MeV
233Ac 233.04455(32)# 145(10) s (1/2+) 1,773.73 MeV
234Ac 234.04842(43)# 44(7) s 1,781.80 MeV
235Ac 235.05123(38)# 40# s 1/2+# 1,780.55 MeV
236Ac 236.05530(54)# 2# min 1,788.62 MeV
值标记#不是纯粹从实验数据得出,但至少部分来自系统的发展趋势。旋转弱任务参数都包含在括号中。 10

丰富

地球 -  脆皮:  0.00000000055 mg/kg = 0.000000000000055% 11

安全信息


材料安全数据表 - ACI Alloys, Inc.

了解更多信息

外部链接:

期刊:
(1) A. Debierne, C. R. Acad. Sci. 129, 593 (1899)
(2) F.O. Geisel, Ber. 55, 3608 (1902)
(3) J.G. Stites, Jr. et al., J. Am. Chem. Soc. 77, 237 (1955)
(4) J.D. Farr et al., J. Inorg. Nucl. Chem. 18, 42 (1961)
(5) O. Hahn, Ber. 40, 1462 (1907)

来源

(1) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:3.
(2) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:132.
(3) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 4:39-4:96.
(4) - Dean, John A. Lange's Handbook of Chemistry, 11th ed.; McGraw-Hill Book Company: New York, NY, 1973; p 4:8-4:149.
(5) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 10:147-10:148.
(6) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 10:178 - 10:180.
(7) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 4:133.
(8) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:193, 12:219-220.
(9) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:123-6:137.
(10) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; pp 6:107-6:122.
(11) - Lide, David R. CRC Handbook of Chemistry and Physics, 84th ed.; CRC Press: Boca Raton, FL, 2002; p 5:5.
(12) - Atomic Mass Data Center. http://amdc.in2p3.fr/web/nubase_en.html (accessed July 14, 2009).
(13) - Lide, David R. CRC Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002; p 14:17.