導入
名: titanium(IV) chloride
* IUPAC
CAS番号: 7550-45-0
モル質量: 189.679 g
重量パーセント: Ti 25.235 %; Cl 74.764 %
分類
• 無機
ボンディング
Ionic Character: 49.09 %
熱化学
ΔHf° (ℓ): -192.2 kcal/mol 1 = -804.16 kJ/mol
ΔHf° (g): -182.4 kcal/mol 1 = -763.16 kJ/mol
S° (ℓ): 60.31 cal/(mol•K) 2 = 252.34 J/(mol•K)
S° (g): 84.8 cal/(mol•K) 2 = 354.80 J/(mol•K)
ΔGf° (ℓ): -176.2 kcal/mol 3 = -737.22 kJ/mol
ΔGf° (g): -173.7 kcal/mol 3 = -726.76 kJ/mol
反応
2 TiO2 (s rutile) + 3 C (s graphite) + 4 Cl2 (g) → 2 TiCl4 (g) + CO2 (g) + 2 CO (g) 4
TiO2 (s rutile) + 1 C (s graphite) + 2 Cl2 (g) → TiCl4 (g) + CO2 (g) 5
詳細については
ソース
(1) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(2) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(3) - Dean, John A. Lange's Handbook of Chemistry, 12th ed.; McGraw-Hill Book Company: New York, NY, 1979; p 9:4-9:94.
(4) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; p 136.
(5) - Ebbing, Darrell D. General Chemistry 3rd ed.; Houghton Mifflin Company: Boston, MA, 1990; p 138.